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Chinese Journal of Organic Chemistry >

2016 , Vol. 36 >Issue 2: 412 - 416

DOI: https://doi.org/10.6023/cjoc201509039

Notes

Atom Transfer Radical Polymerization of Secondary Amine Containing Methacrylate Monomer

  • Jian Zukai ,
  • Yang Yang ,
  • Lang Meidong ,
  • Li Yongjun
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  • a Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237;
    b Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

Received date: 2015-09-19

  Revised date: 2015-10-16

  Online published: 2015-10-26

Supported by

Project supported by the National Natural Science Foundation of China (No. 21204098)

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Abstract

Radical polymer poly(2,2,6,6-tetramethylpiperidinyloxy-4-yl methacrylate) (PTMA), a potential cathode materials, was prepared by radical polymerization of 2,2,6,6-tetramethylpiperidin-4-yl methacrylate (TMPM) containing secondary amine group, followed by oxidation into radical polymer. However, the living radical polymerization of TMPM was hindered by its secondary amine group. The optimized atom transfer radical polymerization condition for TMPM via screening various initiators and catalyst systems was reported, and poly(2,2,6,6-tetramethylpiperidin-4-yl methacrylate)s with different molecular weight were prepared.

Key words： methacrylate; secondary amine; atom transfer radical polymerization

Cite this article

Jian Zukai , Yang Yang , Lang Meidong , Li Yongjun . Atom Transfer Radical Polymerization of Secondary Amine Containing Methacrylate Monomer[J]. Chinese Journal of Organic Chemistry, 2016 , 36(2) : 412 -416 . DOI: 10.6023/cjoc201509039

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