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Chinese Journal of Organic Chemistry >

2016 , Vol. 36 >Issue 3: 502 - 511

DOI: https://doi.org/10.6023/cjoc201510033

Reviews

Advance in Catalytic Asymmetric Conjugate Cyanation

  • Zhou Hongyan ,
  • Li Nana ,
  • Yang Jingya ,
  • Li Tianyuan ,
  • Li Zheng
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  • a College of Science, Gansu Agricultural University, Lanzhou 730070;
    b College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070

Received date: 2015-10-28

  Revised date: 2015-11-25

  Online published: 2015-12-04

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 21362034, 21462038), the Research Fund for the Doctoral Program of Higher Education of China (No. 20136203120005), the University Scientific Research Project of Gansu Province (No. 2013B-003) and the Science and Technology Innovation Fund of Gansu Agricultural University (No. GAU-CX1115).

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Abstract

As one of the most important methods to construct C—C bond in enantioselective manner and afford optically active β-cyano compounds, catalytic asymmetric conjugate cyanation reaction has attracted much attentions worldwide since the first report in 2003. Over the past decade, some important achievements have been made in the catalytic asymmetric conjugate cyanation of α,β-unsaturated imides, α,β-unsaturated N-acylpyrroles, α,β-unsaturated ketones, α,β-unsaturated esters, and nitroalkenes. The research progress in this field is reviewed from both metal catalysis and organocatalysis based on different Michael acceptors.

Key words： asymmetric catalysis; cyanation; Michael addition; α,β-unsaturated compounds; transition metals; organocatalysis

Cite this article

Zhou Hongyan , Li Nana , Yang Jingya , Li Tianyuan , Li Zheng . Advance in Catalytic Asymmetric Conjugate Cyanation[J]. Chinese Journal of Organic Chemistry, 2016 , 36(3) : 502 -511 . DOI: 10.6023/cjoc201510033

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