Chinese Journal of Organic Chemistry >
Agarose Hydrogel Entrapped Trisodium Citrate Catalyzed Multicomponent Reactions for the Synthesis of Benzopyran and Pyranopyrazole Derivatives
Received date: 2015-10-11
Revised date: 2015-11-25
Online published: 2015-12-07
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 21372099, 21072077), the Guangdong Natural Science Foundation (Nos. 10151063201000051, 8151063201000016).
An efficient method for the synthesis of benzopyran derivatives and pyrano[2,3-c]pyrazole derivatives via multicomponent reaction in the presence of agarose hydrogel entrapped trisodium citrate (gel-citrate) as catalyst is developed. The protocol presented here has the merits of easy preparation and handling of catalyst, environmentally benign, simple operation and convenient workup, and excellent yields. Moreover, the catalyst could be recovered and reused at least 6 cycles without apparently losing its activities.
Li Zhipeng , Chen Feiran , Wang Dongyang , Huang Xingtian , Li Yiqun . Agarose Hydrogel Entrapped Trisodium Citrate Catalyzed Multicomponent Reactions for the Synthesis of Benzopyran and Pyranopyrazole Derivatives[J]. Chinese Journal of Organic Chemistry, 2016 , 36(4) : 838 -843 . DOI: 10.6023/cjoc201510010
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