Chinese Journal of Organic Chemistry >
Progress on the Lewis-Basic Organocatalytic Asymmetric Reduction of Imines
Received date: 2015-12-21
Revised date: 2016-01-26
Online published: 2016-02-02
Supported by
Project supported by the Natural Science Foundation of China (Nos. 21376213, 21476194), Zhejiang Provincial Public Technology Research of China (Nos. 2014C31123, 2015C31038) and the Fundamental Research Funds for the Central Universities (No. JUSRP115A05).
Recently, the asymmetric reduction of imines catalyzed by Lewis-basic organocatalyst has been received much attention as the cheap hydrogen source and the simple post treatment. Based on the different functional groups of organocatalysts, this paper introduced formamide, pyridine amide, sulfonamide, supported and other Lewis basic organocatalysts. The structural characteristics, catalytic activity and mechanism of the Lewis-basic organocatalysts were summarized.
Key words： imine; Lewis-base; organocatalyst; asymmetric reduction
Ge Xin , Chen Xinzhi , Qian Chao . Progress on the Lewis-Basic Organocatalytic Asymmetric Reduction of Imines[J]. Chinese Journal of Organic Chemistry, 2016 , 36(6) : 1208 -1217 . DOI: 10.6023/cjoc201512029
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