Chinese Journal of Organic Chemistry >
Cu(I)-Catalyzed Three-Component Reaction of Propargylic Alcohol, Secondary Amines and Atmospheric CO2
Received date: 2015-12-25
Revised date: 2016-01-30
Online published: 2016-02-18
Supported by
Project supported by the National Natural Sciences Foundation of China (Nos. 21472103, 21121002), the Specialized Research Fund for the Doctoral Program of Higher Education (No. 20130031110013) and the National Found for Fostering Talents of Basic Science (No. J1103306).
β-Oxopropylcarbamates constitute an important kind of organic compounds, owing to the extensive applications in agrochemicals, pharmaceuticals, organic synthesis, and protection of amino group. In this article, an efficient and atom-economical Cu(I) catalyzed three-component reaction of propargylic alcohols, secondary amines and CO2 has been developed under atmospheric pressure, affording various β-oxopropylcarbamates in high yields with high selectivity by controlling the concentration of O2. This protocol avoids the use of high pressure of CO2 and provides an extremely simple way to access the synthetically useful β-oxopropylcarbamates.
Li Xuedong , Lang Xiandong , Song Qingwen , Guo Yakun , He Liangnian . Cu(I)-Catalyzed Three-Component Reaction of Propargylic Alcohol, Secondary Amines and Atmospheric CO2[J]. Chinese Journal of Organic Chemistry, 2016 , 36(4) : 744 -751 . DOI: 10.6023/cjoc201512037
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