Chinese Journal of Organic Chemistry >
Advances on the Metallocarbene Formation Reactions Based on Triazole Derivatives
Received date: 2016-01-29
Revised date: 2016-02-28
Online published: 2016-03-18
Supported by
Project supported by the National Natural Science Foundation of China (No. 21462022).
Carbenes are very useful key intermediates in organic synthesis, which generally display high reactivity in chemical transformations. Metallocarbenes can be regarded as metal stabilized organic carbenes. The research progress of the metallocarbene formation and the related reactions based on triazole compounds are reviewed in this work. The RhII-catalyzed metallocarbenes derived from N-sulfonyl-1,2,3-triazoles, as well as the subsequent insertion reactions into other reaction systems to generate new C-C or C-hetero bonds, are specially focused.
Huang Jiapian , Zhou Hao , Chen Zhiyuan . Advances on the Metallocarbene Formation Reactions Based on Triazole Derivatives[J]. Chinese Journal of Organic Chemistry, 2016 , 36(7) : 1555 -1563 . DOI: 10.6023/cjoc201601042
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