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Chinese Journal of Organic Chemistry >

2016 , Vol. 36 >Issue 7: 1501 - 1512

DOI: https://doi.org/10.6023/cjoc201601027

Reviews

Progress on the Asymmetric Diels-Alder Reaction of α,β-Unsaturated Carbonyl Compounds

  • Liu Wenxiang ,
  • Wu Yuqiang ,
  • Li Lingzhi ,
  • Li Xia
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  • a. Pharmaceutial College, Tianjin Medical University, Tianjin 300070;
    b. Department of Pharmaceutical Chemistry, Logistic University of PAP, Tianjin 300309;
    c. Tianjin Key Laboratory for Prevention and Control of Occupational and Environmental Hazards, Tianjin 300309

Received date: 2016-01-20

  Revised date: 2016-03-01

  Online published: 2016-03-28

Supported by

Project supported by the Doctoral Operation Foundation of Medical College of PAP (No. WHB201506) and the Innovative Research Team Program for Scienec and Technology in Logistics University of PAP (No. WHTD201303).

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Abstract

Diels-Alder reaction is a [4+2] concerted cycloaddition reaction, which has attracted considerable attention since its discovery. Asymmetric Diels-Alder reaction is an effective method for synthesis of chiral intermediates, so it was widely applied in the total synthesis of drugs and natural products. α,β-Unsaturated carbonyl compounds are a kind of highly reactive versatile intermediates in organic synthesis, according to its structural characteristics and catalytic types, recent advances in asymmetric normal electron-demand Diels-Alder reaction of α,β-unsaturated carbonyl compounds are reviewed in this paper.

Key words： asymmetric Diels-Alder reaction; natural product; organic synthesis; α,β-unsaturated carbonyl compounds

Cite this article

Liu Wenxiang , Wu Yuqiang , Li Lingzhi , Li Xia . Progress on the Asymmetric Diels-Alder Reaction of α,β-Unsaturated Carbonyl Compounds[J]. Chinese Journal of Organic Chemistry, 2016 , 36(7) : 1501 -1512 . DOI: 10.6023/cjoc201601027

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