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Chinese Journal of Organic Chemistry >

2017 , Vol. 37 >Issue 1: 226 - 231

DOI: https://doi.org/10.6023/cjoc201607007

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Ag2CO3 Mediated Oxidative Dehydrogenative Coupling of Anilines Giving Aromatic Azo Compounds

  • An Yulong ,
  • Tan Hongru ,
  • Zhao Shengyin
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  • College of Chemistry, Chemical and Biological Engineering, Donghua University, Shanghai 201620

Received date: 2016-07-05

  Revised date: 2016-08-17

  Online published: 2016-09-01

Supported by

Project supported by the Natural Science Foundation of Shanghai Municipality(No. 15ZR1401400) and the Fundamental Research Funds for the Central Universities from the Ministry of Education of China(Nos. CUSF-DH-D-2016028, BCZD2016004).

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Abstract

Aromatic azo compounds are widely used as organic dyes,biological medicines,food additives,radical initiators and so on.This paper describes an efficient protocol for the synthesis of aromatic azo compounds from anilines via Ag2CO3 mediated oxidative dehydrogenative coupling reactions in the presence of(CH3)3COK in PhCl.The yields are up to 92%,and this method is easy-operation and provides a practical process to synthesize aromatic azo compounds under mild conditions.

Key words： anilines; Ag2CO3; (CH3)3COK; aromatic azo compounds

Cite this article

An Yulong , Tan Hongru , Zhao Shengyin . Ag2CO3 Mediated Oxidative Dehydrogenative Coupling of Anilines Giving Aromatic Azo Compounds[J]. Chinese Journal of Organic Chemistry, 2017 , 37(1) : 226 -231 . DOI: 10.6023/cjoc201607007

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