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Chinese Journal of Organic Chemistry >

2017 , Vol. 37 >Issue 1: 92 - 96

DOI: https://doi.org/10.6023/cjoc201607034

ARTICLE

A Reaction-Based Chemsensor for Hydrogen Sulfide Detection with Fluorescence Enhancement

  • Zhou Chan ,
  • Qiu Bo ,
  • Zeng Yi ,
  • Chen Jinping ,
  • Yu Tianjun ,
  • Li Yi
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  • Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190

Received date: 2016-07-20

  Revised date: 2016-10-08

  Online published: 2016-10-18

Supported by

Project supported by the the National Natural Science Foundation of China(No. 21233011) and the State Key Development Program for Basic Research of China(973 Program, Nos. 2013CB834703, 2013CB834505).

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Abstract

A reaction-based probe 8-(2,4-dinitrophenoxy) pyrene-1-carbaldehyde(PCNP) for H2S detection was designed and synthesized by utilizing 8-hydroxypyrene-1-carbaldehyde and dinitrophenyl ether as the reporting chromophore and the recognition unit,respectively.The probe was dissolved in phosphate buffer saline(PBS) with cetyltrimethyl ammonium bromide(CTAB),and the sensing ability toward H2S was investigated with steady-state spectroscopy.The emission of PCNP was quenched by photoinduced electron transfer without H2S.The fluorescence of PCNP was boosted after thiolysis reaction in the presence of H2S,showing orange red emission.The fluorescence response was rapid and reached a maximum enhancement of about 260 times in the presence of 0.1 mmol·L-1 H2S,giving a reaction rate constant of 0.20 min-1.The limit of detection of PCNP is estimated to be 0.10 μmol·L-1.The results demonstrate that PCNP is capable of detecting H2S rapidly,sensitively and selectively.

Cite this article

Zhou Chan , Qiu Bo , Zeng Yi , Chen Jinping , Yu Tianjun , Li Yi . A Reaction-Based Chemsensor for Hydrogen Sulfide Detection with Fluorescence Enhancement[J]. Chinese Journal of Organic Chemistry, 2017 , 37(1) : 92 -96 . DOI: 10.6023/cjoc201607034

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