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Chinese Journal of Organic Chemistry >

2017 , Vol. 37 >Issue 3: 753 - 758

DOI: https://doi.org/10.6023/cjoc201610002

Notes

Pt/WO3/ZrO2-Catalyzed Selective Hydrogenolysis of Glycerol to Produce 1,3-Propanediol

  • Tong Qing ,
  • Gao Qiang ,
  • Xu Bolian ,
  • Yu Lei ,
  • Fan Yining
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  • a Key Laboratory of Mesoscopic Chemistry of Ministry of Education, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093;
    b Nanjing University-Yangzhou Chemistry and Chemical Engineering Institute, Yangzhou 211400;
    c School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002

Received date: 2016-10-01

  Revised date: 2016-11-16

  Online published: 2016-11-29

Supported by

Project supported by the National Natural Science Fundation of China (No. 21202141), the Priority Academic Program Development of Jiangsu Higher Education Institutions, and the Key Science & Technology Specific Projects of Yangzhou (No. YZ20122029).

Fold

Abstract

Glycerol is an abundantly generated biomass and conversion of this compound into useful chemicals is of significant industrial value. Hydrogenolysis of glycerol produces a series of C-3 alcohols, such as 1-propanol, 2-propanol, 1,2-pro-panediol and 1,3-propanediol (1,3-PDO). Among these compounds, 1,3-PDO is an important organic intermediate to synthesize poly-trimethylene-terephthalate. Therefore, synthesis of 1,3-PDO through the selective hydrogenolysis of glycerol is a promising subject. Recently, during our investigations on the Pt/WO3/ZrO2-catalyzed glycerol hydrolysis, it was found that the acidity of the catalyst could be controlled by tungsten oxide content and the glycerol conversion was largely improved with high 1,3-PDO selectivity. The technology largely improved the synthetic efficiency and is of potential industrial application value.

Key words： glycerol; hydrogenolysis; catalysis; biomass; 1,3-propanediol

Cite this article

Tong Qing , Gao Qiang , Xu Bolian , Yu Lei , Fan Yining . Pt/WO3/ZrO2-Catalyzed Selective Hydrogenolysis of Glycerol to Produce 1,3-Propanediol[J]. Chinese Journal of Organic Chemistry, 2017 , 37(3) : 753 -758 . DOI: 10.6023/cjoc201610002

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