Chinese Journal of Organic Chemistry >
Rhodium(Ⅰ)-Catalyzed Stereospecific [3+2] Cycloadditions of Vinylaziridines and Ynamides
Received date: 2017-01-21
Revised date: 2017-02-16
Online published: 2017-02-20
Supported by
Project supported by the Shanghai Sailing Program (No. 15YF1403600) and the National Natural Science Foundation of China (Nos. 21602062, 21373088, 21425205).
The first rhodium-catalyzed stereospecific intermolecular [3+2] cycloaddition reaction of vinylaziridines with ynamides was realized. The salient features of the transformation include broad substrate scope, mild reaction condition, and simple operation. Moreover, the chirality of vinylaziridines can be completely transferred to the cycloadducts, representing an atom-economic and enantiospecific protocol for the construction of valuable 2-amino pyrroline derivatives.
Zhu Chaoze , Feng Jianjun , Zhang Junliang . Rhodium(Ⅰ)-Catalyzed Stereospecific [3+2] Cycloadditions of Vinylaziridines and Ynamides[J]. Chinese Journal of Organic Chemistry, 2017 , 37(5) : 1165 -1172 . DOI: 10.6023/cjoc201701043
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