Chinese Journal of Organic Chemistry >
Hydrogenation of Alkynes to cis-Alkenes with Hydrazine in Air
Received date: 2017-01-20
Revised date: 2017-02-19
Online published: 2017-02-27
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 21372059, 21572044), and the Natural Science Foundation of Hebei Province (Nos. B2016201254, 2016201031).
Transfer hydrogenation is a mild and effective way in reduction reaction. In this paper, a simple approach of selectively hydrogenation of alkynes to cis-alkenes with NH2NH2·H2O as a transfer hydrogenation agent in the presence of air without any catalysts or metals was developed. Furthermore, the configuration of cis-alkene was confirmed by the 2D NOESY spectrum.
Key words： transfer hydrogenation; hydrazine; alkynes; alkenes; diazene
Wang Jintao , Xiong Jiukai , Li Juanjuan , Wang Jiali , Wang Kerang , Li Xiaoliu . Hydrogenation of Alkynes to cis-Alkenes with Hydrazine in Air[J]. Chinese Journal of Organic Chemistry, 2017 , 37(6) : 1407 -1411 . DOI: 10.6023/cjoc201701040
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