Chinese Journal of Organic Chemistry >
Synthesis of Olefinic Carbolong Complexes
Received date: 2017-03-01
Revised date: 2017-03-17
Online published: 2017-04-10
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 21490573, 21332002, 21472156).
Carbolong complexes are a new type of metalla-aromatic compounds with novel skeleton and interesting properties, which could be used as potential interesting materials. However, most of them do not have reactive organic functional groups, which hinder their applications as functional materials via chemical modifications. Olefinic group is a reactive functional group that can be used for polymerization or click reaction and so on. In this work, the synthesis of carbolong complexes attached an olefinic group, which could be used to prepare carbolong-containing materials, is reported based on their reactivity.
Key words： carbolong; metallapentalyne; metallapentalene; olefinic; osmium
Lu Zhengyu , Chen Jiangxi , Xia Haiping . Synthesis of Olefinic Carbolong Complexes[J]. Chinese Journal of Organic Chemistry, 2017 , 37(5) : 1181 -1188 . DOI: 10.6023/cjoc201703003
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