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Chinese Journal of Organic Chemistry >

2017 , Vol. 37 >Issue 10: 2745 - 2751

DOI: https://doi.org/10.6023/cjoc201704001

ARTICLE

Fluorination Reaction of P(Ⅲ) Compounds with the Electrophilic Fluorinating Reagent Selectfluor

  • Huang Yulin ,
  • Chen Qian
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  • a School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006;
    b Key Laboratory of Functional Molecular Engineering of Guangdong Province, South China University of Technology, Guangzhou 510640

Received date: 2017-04-01

  Revised date: 2017-05-10

  Online published: 2017-06-02

Supported by

Project supported by the Science and Technology Planning Project of Guangdong Province (No.2015A020211026),the 100 Young Talents Program of Guangdong University of Technology (No.220413506) and the Open Fund of the Key Laboratory of Functional Molecular Engineering of Guangdong Province (No.2016kf07).

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Abstract

A fluorination reaction of P(Ⅲ) compounds with the electrophilic fluorinating reagent Selectfluor is described. The reaction proceeded in acetonitrile/water at room temperature for 15~60 min to afford phosphoric fluorides in 34%~81% yields.

Key words： P(Ⅲ) compound; electrophilic fluorinating reagent; fluorination reaction; phosphoric fluoride

Cite this article

Huang Yulin , Chen Qian . Fluorination Reaction of P(Ⅲ) Compounds with the Electrophilic Fluorinating Reagent Selectfluor[J]. Chinese Journal of Organic Chemistry, 2017 , 37(10) : 2745 -2751 . DOI: 10.6023/cjoc201704001

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