Chinese Journal of Organic Chemistry >
Syntheses and Photovoltaic Performance of N-Phenylcarbazole Sensitizers with Benzothiadiazole Auxiliary Acceptor
Received date: 2017-04-27
Revised date: 2017-07-13
Online published: 2017-08-11
Supported by
Project supported by the National Natural Science Foundation of China (No. 21406202).
Four N-phenylcarbazole sensitizers were designed and synthesized with N-phenylcarbazole as the electron donor, benzothiadiazole as the auxiliary acceptor, thiophene or benzene as π bridge, cyanoacetic acid or rhodanine acetic acid as the an-choring acceptor. The spectral properties and photovoltaic performance of the sensitizers were investigated. Though with short maximum absorption wavelength and low molar extinction coefficient, dyes with cyanoacetic acid acceptor show higher electron injection efficiency than dyes with rhodanine acetic acid acceptor, and hence obtain superior photocurrent and photovoltage. Dyes with benzene bridge exhibit higher photocurrent and photovoltage than dyes with thiophene bridge. Therefore, among four sensitizers, dye with benzene bridge and cyanoacetic acid acceptor obtains better photoelectric conversion efficiency of 5.28% (JSC=9.14 mA/cm2, VOC=0.74 V, FF=0.78).
Han Liang , Wu Liang , Tong Yongzheng , Zu Xiaoyan , Jiang Shaoliang . Syntheses and Photovoltaic Performance of N-Phenylcarbazole Sensitizers with Benzothiadiazole Auxiliary Acceptor[J]. Chinese Journal of Organic Chemistry, 2017 , 37(11) : 2940 -2947 . DOI: 10.6023/cjoc201704045
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