Chinese Journal of Organic Chemistry >
Synthesis of a Pd-Pyridine N-Heterocyclic Carbene Complex (NHC)-PdCl2(Py) and Its Efficient Application in Coupling Reaction
Received date: 2017-05-17
Revised date: 2017-07-13
Online published: 2017-08-11
Supported by
Project supported by the National Natural Science Foundation of China (No. 21402067).
A Pd-pyridine N-heterocyclic carbene complex (NHC)PdCl2(Py) has been synthesized through two steps and successfully applied as an effective catalyst for the Suzuki coupling reaction, Heck coupling reaction and Sonogashira coupling reaction. The catalyst demonstrates excellent catalytic activity in Suzuki coupling reaction and Sonogashira coupling reaction with a catalyst loading of 0.1 mol% and 1 mol% in Heck coupling reaction.
Key words： carbene; suzuki coupling; Heck coupling; Sonogashira coupling
Yuan Hang , Chen Huilian , Luo Zhibin , Gao Yuhua , Lu Hongfei . Synthesis of a Pd-Pyridine N-Heterocyclic Carbene Complex (NHC)-PdCl2(Py) and Its Efficient Application in Coupling Reaction[J]. Chinese Journal of Organic Chemistry, 2017 , 37(11) : 2948 -2955 . DOI: 10.6023/cjoc201705027
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