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Chinese Journal of Organic Chemistry >

2017 , Vol. 37 >Issue 12: 3220 - 3228

DOI: https://doi.org/10.6023/cjoc201705023

Articles

Iodine Catalyzed Kabachnik-Fields Reaction of Trialkyl Phosphites: Facile Access to Benzoxazine Containing Phosphorus

  • Wang Yufeng ,
  • Yang Yajie ,
  • Huang Ling ,
  • Jie Kun ,
  • Guo Shengmei ,
  • Cai Hua
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  • a College of Chemistry, Nanchang University, Nanchang 330031;
    b The First College of Clinical Medicine, Nanchang University, Nanchang 330031

Received date: 2017-05-16

  Revised date: 2017-07-13

  Online published: 2017-08-16

Supported by

Project supported by the National Program on Key Basic Research Project (973 Program, No. 2012CBA01204), the National Natural Science Foundation of China (No. 21302084) and the Natural Science Foundation of Jiangxi Province (No. 20151BAB213007).

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Abstract

Iodine-catalyzed Kabachnik-Fields reaction with trialkyl phosphites for the synthesis of α-amino phosphates was developed. This transformation completes rapidly at 40℃, and is well tolerated with a range of amines and phosphites. Moreover, the products afforded by salicyl aldehydes with trialkyl phosphites could efficiently convert to benzoxazines containing phosphate under mild conditions, which provide a new precursor of new phenolic resin

Key words： trialkyl phosphite; benzoxazineis; Kabachnik-Fields reaction; iodine

Cite this article

Wang Yufeng , Yang Yajie , Huang Ling , Jie Kun , Guo Shengmei , Cai Hua . Iodine Catalyzed Kabachnik-Fields Reaction of Trialkyl Phosphites: Facile Access to Benzoxazine Containing Phosphorus[J]. Chinese Journal of Organic Chemistry, 2017 , 37(12) : 3220 -3228 . DOI: 10.6023/cjoc201705023

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