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Chinese Journal of Organic Chemistry >

2018 , Vol. 38 >Issue 1: 277 - 280

DOI: https://doi.org/10.6023/cjoc201707023

Notes

Synthesis, Structure and Coordination Chemistry of an α-Iminophosphaferrocene

  • Hao Yanwei ,
  • Tian Rongqiang ,
  • Wu Di ,
  • Duan Zheng ,
  • Mathey Franç ,
  • ois
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  • a International Phosphorus Laboratory, International Joint Research Laboratory for Functional Organophosphorus Materials of Henan Province, College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001;
    b Key Laboratory for Advanced Silicon Carbide Materials, Research Center of Functional Materials, Kaifeng University, Kaifeng 475001

Received date: 2017-07-21

  Revised date: 2017-09-09

  Online published: 2017-09-15

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 21302174, 21672193, 21272218), the Young Talent Research Fund of Zhengzhou University (No. 1621316006) and the Zhengzhou University of China.

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Abstract

An 2-iminophospholide 1 can be obtained via two [1,5] shifts by reaction of potassium tert-butoxide with 3,4-di- methyl-1-phenylphosphole and an imidoyl chloride. The reaction of 1 with [Cp*FeCl]n affords a 2-iminophosphaferrocene 2 which behaves as a P,N chelating ligand toward Mo(CO)4 and Rh(CO)2]+. The X-ray crystal structures of 2 and its Mo complex have been recorded.

Key words： phosphaferrocene; imine; coordination chemistry

Cite this article

Hao Yanwei , Tian Rongqiang , Wu Di , Duan Zheng , Mathey Franç , ois . Synthesis, Structure and Coordination Chemistry of an α-Iminophosphaferrocene[J]. Chinese Journal of Organic Chemistry, 2018 , 38(1) : 277 -280 . DOI: 10.6023/cjoc201707023

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