Chinese Journal of Organic Chemistry >
Chiral Urea Derivatives Organocatalyzed Asymmetric aza-Friedel-Crafts Reaction of α-Naphthol with N-Tosyl Aldimines
Received date: 2017-08-15
Revised date: 2017-10-15
Online published: 2017-11-17
Supported by
Project supported by the National Natural Science Foundation of China (No. 21102055), the Department of Education of Jilin Province (No. JJKH20170409KJ) and the National Students' Program for Innovation and Entrepreneurship Training (No. 201713743010).
Chiral urea derivatives as organocatalysts were applied in the asymmetric aza-Friedel-Crafts reaction of α-naphthol with 14 N-tosyl aldimines. The desired chiral aminoarylnaphthols were obtained in 70%~86% yields with up to 78% enantiomeric excess (ee) under the screened optimal condition. The catalyst type and the substrate scope were broadened in this methodology.
Wang Liming , Lin Geng , Zhao Meijun , Liu Dongyao , Jin Ying . Chiral Urea Derivatives Organocatalyzed Asymmetric aza-Friedel-Crafts Reaction of α-Naphthol with N-Tosyl Aldimines[J]. Chinese Journal of Organic Chemistry, 2018 , 38(3) : 642 -647 . DOI: 10.6023/cjoc201708028
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