Chinese Journal of Organic Chemistry >
Visual Discrimination of Phosphate Anion via Selective Metallo-Hydrogel Formation
Received date: 2017-09-29
Revised date: 2017-11-11
Online published: 2017-11-21
Supported by
Project supported by the National Key R&D Program of China (No. 2016YFA0202902) and the National Natural Science Foundation of China (No. 21572036).
Due to high selective coordination ability of phosphate anion to the Zn center of pincer type terpyridine zinc nitrate complexes, intriguing visual recognition of phosphate anion via selective metallo-hydrogel formation has been successfully realized. Based on this interesting result, a series of control experiments were conducted including the study on thermodynamic stability, rheological property and microscopic morphology of the metallo-hydrogel, a plausible mechanism of the discrimination was proposed.
Wu Yan , Zhang Yang , Wu Jiajie , Zhou Jun , Liu Hong , Tu Tao . Visual Discrimination of Phosphate Anion via Selective Metallo-Hydrogel Formation[J]. Chinese Journal of Organic Chemistry, 2018 , 38(3) : 705 -709 . DOI: 10.6023/cjoc201709048
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