Chinese Journal of Organic Chemistry >
Synthesis of Phosphine Ligands Based on 5-Amino-o-cresol and Its Application in Ethylene Oligomerization
Received date: 2017-06-09
Revised date: 2017-07-28
Online published: 2017-11-28
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 51534004, U1362110), and the Program for New Century Excellent Talents in University (No. NCET-07-0142).
A phosphorus ligand containing PNP and P-O structure was synthesized by substitution reaction of 5-amino-o-cresol with chlorodiphenylphosphine and its structure was conformed. Its in situ prepared complex with Cr(acac)3 and preformed complex with CrCl3(THF)3 were used as main catalysts in catalyzing ethylene oligomerization, accompanied with methylaluminoxane (MAO) as cocatalyst. The effects of solvent, temperature, pressure and Al/Cr molar ratio on the activity and selectivity of the catalyst were investigated and compared with the in situ formation of 2-aminophenol and 4-aminophenol phosphine ligands catalytic system of catalyzing ethylene oligomerization effect. The experimental results showed that the activity reached 5.91×106 g/(mol·Cr·h), when the reaction was carried at 50℃ with reaction pressure of 2.5 MPa and the Al/Cr molar ratio of 700. The selectivity of 1-octene was 72.94% and the total selectivity of 1-hexene and 1-octene was 82.11%.
Feng Zhichao , Mao Guoliang , Wu Wei , Luo Mingjian , Liu Yang . Synthesis of Phosphine Ligands Based on 5-Amino-o-cresol and Its Application in Ethylene Oligomerization[J]. Chinese Journal of Organic Chemistry, 2018 , 38(3) : 698 -704 . DOI: 10.6023/cjoc201706010
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