Chinese Journal of Organic Chemistry >
Metal-Free Esterification of Aldehydes or Carboxylic Acids with Quaternary Ammonium Salts
Received date: 2017-10-26
Revised date: 2017-11-26
Online published: 2017-12-05
Supported by
Project supported by the National Natural Science Foundation of China (No. 21462031) and the Program for Young Talents of Science and Technology in Universities of Inner Mongolia Autonomous Region (No. NJYT-17-A22).
A metal-free esterification of various aldehydes or carboxylic acids with quaternary ammonium salts has been developed for selective synthesis of esters. A possible mechanism containing radical process that aldehyde converts to carboxylic acid and the generation of iodohydrocarbon via C-N bond cleavage of quaternary ammonium salt is proposed.
Key words： quaternary ammonium salt; esterification; aldehyde
Menggen qiqige , Wu Yun , Bao Yongsheng . Metal-Free Esterification of Aldehydes or Carboxylic Acids with Quaternary Ammonium Salts[J]. Chinese Journal of Organic Chemistry, 2018 , 38(4) : 902 -911 . DOI: 10.6023/cjoc201710034
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