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Chinese Journal of Organic Chemistry >

2018 , Vol. 38 >Issue 6: 1341 - 1349

DOI: https://doi.org/10.6023/cjoc201801037

Reviews

Transition-Metal-Catalyzed Guanylation Reaction of Amines with Carbodiimides Constructing Guanidines

  • Wang Lianjun ,
  • Chi Yue ,
  • Zhang Wenxiong ,
  • Xi Zhenfeng
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  • a School of Chemistry and Chemical Engineering, Hunan Institute of Engineering, Xiangtan 411104;
    b College of Chemistry and Molecular Engineering, Peking University, Beijing 100871

Received date: 2018-01-26

  Revised date: 2018-02-14

  Online published: 2018-02-28

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 21725201, 21572005).

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Abstract

Guanidine derivatives are an important class of nitrogen-containing organic compounds, which are widely used in various pharmaceuticals, agrochemicals, sweeteners, explosives, and so on. Although classical methods for the synthesis of guanidines are established, there are still many fatal shortcomings which need to be resolved. In recent years, it has been gradually turned to the direct catalytic guanylation reaction of amines with carbodiimides. In this paper, the recent progress in transition-metal-catalyzed guanylation reaction of amines with carbodiimides to construct acyclic or cyclic guanidines based on the catalytic reaction mechanism, reaction system, the scope of substrates, etc. is reviewed.

Key words： guanylation reaction; guanidines; amines; carbodiimides

Cite this article

Wang Lianjun , Chi Yue , Zhang Wenxiong , Xi Zhenfeng . Transition-Metal-Catalyzed Guanylation Reaction of Amines with Carbodiimides Constructing Guanidines[J]. Chinese Journal of Organic Chemistry, 2018 , 38(6) : 1341 -1349 . DOI: 10.6023/cjoc201801037

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