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Chinese Journal of Organic Chemistry >

2018 , Vol. 38 >Issue 10: 2780 - 2783

DOI: https://doi.org/10.6023/cjoc201802018

Notes

Copper-Catalyzed Aerobic Oxidation Reaction of Benzyl Alcohol in Water under Base-Free Condition

  • Yang Xiaojiang ,
  • Mao Jincheng ,
  • Zhang Heng ,
  • Zhang Yang ,
  • Mao Jinhua
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  • State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu 610500

Received date: 2018-02-12

  Revised date: 2018-04-13

  Online published: 2018-06-01

Supported by

Project supported by the Sichuan Youth Science & Technology Foundation (No. 2017JQ0010), the National High Technology Research & Development Program (No. 2016ZX05053), the Key Fund Project of Educational Commission of Sichuan Province (No. 16CZ0008), the Explorative Project Fund of the State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation (Southwest Petroleum University) (No. G201601).

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Abstract

A green and very mild method for the oxidation of benzyl alcohols to aromatic aldehydes with excellent conversions has been developed. The reaction could be carried out directly in air at room temperature and was catalyzed by bis (8-quinolinolato) copper (Ⅱ) with 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) as co-catalysts. The methodology provided a practical approach for the synthesis of aromatic aldehydes, which has the advantages of environment-friendly, simple workup and high yields.

Key words： benzyl alcohol; aromatic aldehyde; copper; TEMPO; aerobic oxidation

Cite this article

Yang Xiaojiang , Mao Jincheng , Zhang Heng , Zhang Yang , Mao Jinhua . Copper-Catalyzed Aerobic Oxidation Reaction of Benzyl Alcohol in Water under Base-Free Condition[J]. Chinese Journal of Organic Chemistry, 2018 , 38(10) : 2780 -2783 . DOI: 10.6023/cjoc201802018

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