Chinese Journal of Organic Chemistry >
Synthesis of Osmium Complexes with Bidentate Nitrogen-Based Ligands and Their Application in Catalytic Dehydrogenation of Ammonia Borane
Received date: 2018-05-28
Revised date: 2018-07-10
Online published: 2018-08-14
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 21501048, 21503070, 21571052, 21771057) and the Key Science and Technology Project of Henan Province (No.182102210377).
Reactions of OsCl2(PPh3)3 (1) with bidentate nitrogen-based ligands at room temperature led to the formation of complexes OsCl2(PPh3)2(diamine) (2~6) and OsCl2(PPh3)2(Phen*) (7~11). Complexes 2~11 showed high activity in the catalytic dehydrogenation of ammonia borane at 60℃, in THF/DME (V:V=1:1.6) solution with the catalyst loading of 5 mol%. Among all the catalysts, compound 4 demonstrated the highest catalytic activity, which represents the most efficient osmium catalyst in catalytic dehydrogenation of ammonia borane until now.
Key words： osmium; complex; synthesis; catalytic dehydrogenation; ammonia borane
Zhao Qianyi , Liang Yuan , Xu Ting , Dou Ting , Zhang Jie , Chen Xuenian . Synthesis of Osmium Complexes with Bidentate Nitrogen-Based Ligands and Their Application in Catalytic Dehydrogenation of Ammonia Borane[J]. Chinese Journal of Organic Chemistry, 2018 , 38(12) : 3286 -3295 . DOI: 10.6023/cjoc201805050
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