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Chinese Journal of Organic Chemistry >

2019 , Vol. 39 >Issue 2: 475 - 481

DOI: https://doi.org/10.6023/cjoc201808013

ARTICLE

Palladium Catalyzed Allylic Amination of Cinnamyl Carbonates with Acyl Hydrazones

  • Liu Lantao ,
  • Chen Yingyinga ,
  • Zhang An'an ,
  • Liu Xue ,
  • Zhang Li ,
  • Bai Jingru ,
  • Li Heng ,
  • Mao Guoliang
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  • a College of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu 476000;
    b College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318;
    c College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001

Received date: 2018-08-13

  Revised date: 2018-09-03

  Online published: 2018-09-10

Supported by

Project supported by the National Natural Science Foundation of China (No. 21572126), the Program for Science & Technology Innovation Talents in Universities of Henan Province (No. 14HASTIT016) and the Program of Science and Technology Innovation Talents of Henan Province (No. 2018JQ0011).

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Abstract

Allylic amines moiety exists extensively in natural products, medicines and functional materials. In addition, they are also a kind of versatile building blocks for organic synthesis. Using CH3CN as solvent, the palladium catalyzed allyl amination of cinnamyl carbonate and acylhydrazone compounds was realized under argon. The linear product was formed selectively and the up to 99% yield was obtained. The reaction has features of base free, mild reaction condition, simple operation and broad substrate scope.

Key words： paladium catalysis; allylic amination; cinnamyl carbonate

Cite this article

Liu Lantao , Chen Yingyinga , Zhang An'an , Liu Xue , Zhang Li , Bai Jingru , Li Heng , Mao Guoliang . Palladium Catalyzed Allylic Amination of Cinnamyl Carbonates with Acyl Hydrazones[J]. Chinese Journal of Organic Chemistry, 2019 , 39(2) : 475 -481 . DOI: 10.6023/cjoc201808013

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