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Chinese Journal of Organic Chemistry >

2019 , Vol. 39 >Issue 4: 1070 - 1078

DOI: https://doi.org/10.6023/cjoc201809011

Articles

Copper-Catalyzed Oxidative Cross-Coupling Reactions for the Synthesis of β-Acyl-α-amino Acid Derivatives in Aqueous Medium

  • Zhou Anxi ,
  • Zhou Xiaofei ,
  • Mao Liuliang ,
  • Zheng Dagui ,
  • Zhu Xianhong ,
  • Chen Zongbao
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  • a Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, Shangrao Normal University, Shangrao 334001;
    b Key Laboratory of Organic Chemistry in Jiangxi Province, Institute of Organic Chemistry, Jiangxi Science & Technology Normal University, Nanchang 330013

Received date: 2018-09-06

  Revised date: 2018-12-10

  Online published: 2018-12-21

Supported by

Project supported by the Science and Technology Research Projects of the Education Department of Jiangxi Province (No.GJJ161059),the Key R&D Project of Jiangxi Province (No.20161BBF60042) and the Academic Research Project for College Students of Shangrao Normal University (No.XS201723).

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Abstract

A novel copper-catalyzed oxidative cross-coupling reaction between N-arylglycine esters and Silyl enol ethers for the synthesis of β-acyl-α-amino acid esters has been developed. The features of this reaction are high reaction yields, mild reaction conditions (such as room temperature environments and inexpensive catalysts, etc.) and smooth operation in aqueous medium.

Key words： copper-catalyzed; coupling reactions; amino acid derivatives; synthesis

Cite this article

Zhou Anxi , Zhou Xiaofei , Mao Liuliang , Zheng Dagui , Zhu Xianhong , Chen Zongbao . Copper-Catalyzed Oxidative Cross-Coupling Reactions for the Synthesis of β-Acyl-α-amino Acid Derivatives in Aqueous Medium[J]. Chinese Journal of Organic Chemistry, 2019 , 39(4) : 1070 -1078 . DOI: 10.6023/cjoc201809011

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