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Chinese Journal of Organic Chemistry >

2019 , Vol. 39 >Issue 5: 1411 - 1416

DOI: https://doi.org/10.6023/cjoc201810010

Articles

Potassium Phenyltrifluoroborate-Catalyzed Reduction of Aldehydes and Ketones into Alcohol with Silanes

  • Liu Jianhui ,
  • Wang Xingyang
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  • a State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024;
    b School of Petroleum and Chemical Engineering, Dalian University of Technology, Panjin Campus, Panjin 124221

Received date: 2018-10-11

  Revised date: 2018-12-12

  Online published: 2019-01-18

Supported by

Project supported by the State Key Laboratory of Fine Chemicals (Panjin) (No. JH2014009) and the Fundamental Research Funds for the Central Universities.

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Abstract

The selective reduction of carbonyl group with organosilane as reducing agent was studied with methanol as a solvent under the action of 2.5 mol% C6H5BF3K and 2.2 epuiv. (EtO)3SiH. The target products were obtained in medium to high yield. This method shows good selectivity and provides a new method for carbonyl reduction.

Key words： carbonyl reduction; organosilane; potassium phenyl trifluoroborate

Cite this article

Liu Jianhui , Wang Xingyang . Potassium Phenyltrifluoroborate-Catalyzed Reduction of Aldehydes and Ketones into Alcohol with Silanes[J]. Chinese Journal of Organic Chemistry, 2019 , 39(5) : 1411 -1416 . DOI: 10.6023/cjoc201810010

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