Chinese Journal of Organic Chemistry >
Electrochemical Synthesis of Tetrasubstituted Hydrazines by Dehydrogenative N-N Bond Formation
Received date: 2018-12-04
Revised date: 2018-12-27
Online published: 2019-01-18
Supported by
Project supported by the National Natural Science Foundation of China (No. 21672178) and the National Foundation for Fostering Talents in Basic Science (No. J1310024).
An electrochemical synthesis of tetrasubstituted hydrazines through dehydrogenative dimerization of secondary amines has been developed. The reactions are conducted in a simple undivided cell with constant current. The use of electricity to promote the reactions obviates the need for transition metal catalysts and oxidizing reagents, providing an efficient and sustainable access to tetrasubstituted hydrazines with diverse electronic properties.
Feng Enqi , Hou Zhongwei , Xu Haichao . Electrochemical Synthesis of Tetrasubstituted Hydrazines by Dehydrogenative N-N Bond Formation[J]. Chinese Journal of Organic Chemistry, 2019 , 39(5) : 1424 -1428 . DOI: 10.6023/cjoc201812007
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