Chinese Journal of Organic Chemistry >
Study on the Chlorination Reaction of Hydrazones by Using of Trichloroisocyanuric Acid as Chloride Source
Received date: 2018-11-30
Revised date: 2019-01-17
Online published: 2019-01-31
Supported by
Project supported by the National Natural Science Foundation of China (No. 21662030).
The chlorination reaction of hydrazones with N-aryltrifluoroacetohydrazones by using trichloroisocyanuric acid as chlorine source was investigated, and a series of N-arylhydrazonyl chlorides and N-aryltrifluoroacetohydrazonyl chlorides were obtained in high yields. This method had advatages of easy operation, short reaction time, mild conditions and the use of stable and cheap chlorine source, which provides an efficiant method for the synthesis of N-arylhydrazonyl chlorides and N-aryltrifluoroacetohydrazonyl chlorides.
Zong Wuzhong , Hu Yulai , Wang Xiaoping , Liu Jiaxin , Huang Danfeng , Wang Kehu . Study on the Chlorination Reaction of Hydrazones by Using of Trichloroisocyanuric Acid as Chloride Source[J]. Chinese Journal of Organic Chemistry, 2019 , 39(5) : 1396 -1403 . DOI: 10.6023/cjoc201811039
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