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Chinese Journal of Organic Chemistry >

2019 , Vol. 39 >Issue 6: 1761 - 1766

DOI: https://doi.org/10.6023/cjoc201901015

Articles

Copper-Promoted Direct Nitration of Arenes Assisted by an N,O-Bidentate Directing System

  • Wang Yunlong ,
  • Zhang Linbao ,
  • Niu Junlong ,
  • Song Maoping
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  • a College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001;
    b College of Chemistry and Molecular Engineering, Qingdao University of Science & Technology, Qingdao 266042

Received date: 2019-01-11

  Revised date: 2019-02-25

  Online published: 2019-03-08

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 21772179, 21672192), the Program for Science & Technology Innovation Talents in Universities of Henan Province (No. 19HASTIT038).

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Abstract

Cu(Ⅱ)-promoted C-H nitration of arenes has been disclosed with the aid of N,O-bidentate directing group. The protocol was operationally simple by using NaNO2as the nitration source. Various amide substrates were tolerated in the reaction system, which establishes opportunities for developing simple and facile methods, and enriches the strategies to access aromatic nitro derivatives.

Key words： C-H activation; bidentate direction; Cu-catalyzed; nitration

Cite this article

Wang Yunlong , Zhang Linbao , Niu Junlong , Song Maoping . Copper-Promoted Direct Nitration of Arenes Assisted by an N,O-Bidentate Directing System[J]. Chinese Journal of Organic Chemistry, 2019 , 39(6) : 1761 -1766 . DOI: 10.6023/cjoc201901015

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