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Chinese Journal of Organic Chemistry >

2019 , Vol. 39 >Issue 8: 2338 - 2342

DOI: https://doi.org/10.6023/cjoc201902016

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Isolation and Characterization of a Trinuclear Rare-Earth Metal Complex Containing a Bicyclo[3.1.0]-P64- Ligand

  • Du Shanshan ,
  • Chai Zhengqi ,
  • Hu Jingyuan ,
  • Zhang Wen-Xiong ,
  • Xi Zhenfeng
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  • Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871

Received date: 2019-02-18

  Revised date: 2019-03-25

  Online published: 2019-04-08

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 21725201, 21890721, 21572005).

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Abstract

Direct synthesis of organophosphorus compounds from white phosphorus (P4) is of great significance because this process avoids the industry pollution synthetic methods and provides the possibilities for many novel phosphorus-containing compounds. A trinuclear rare-earth metal complex[{(η5-C5Me5)LuCl}3(THF)P6] [Li(THF)4] from lutetacyclopentadiene mediated P4 functionalization was isolated and characterized. This novel complex contains a bicyclo[3.1.0]-P64- ligand which is an unreported type. X-ray diffraction analysis shows that the bicyclo[3.1.0]-P64- ligand adopts a boat-like conformation. Three lutetium atoms coordinate to this ligand in η1, η3, η3 mode, respectively, and a novel[P6Lu3] cage has been formed. Density functional theory (DFT) calculations indicate that there are two three-center two-electron bonds.

Key words： polyphosphorus ligand; white phosphorus activation; rare-earth-metal complex

Cite this article

Du Shanshan , Chai Zhengqi , Hu Jingyuan , Zhang Wen-Xiong , Xi Zhenfeng . Isolation and Characterization of a Trinuclear Rare-Earth Metal Complex Containing a Bicyclo[3.1.0]-P64- Ligand[J]. Chinese Journal of Organic Chemistry, 2019 , 39(8) : 2338 -2342 . DOI: 10.6023/cjoc201902016

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