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Chinese Journal of Organic Chemistry >

2019 , Vol. 39 >Issue 6: 1568 - 1582

DOI: https://doi.org/10.6023/cjoc201903044

Reviews

Recent Advances in Asymmetric Hydroformylation

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  • a Key Laboratory of Biomedical Polymers of Ministry of Education, College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072;
    b Engineering Research Center of Organosilicon Compounds & Materials, Ministry of Education, College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072;
    c Department of Chemistry, Southern University of Science and Technology, Shenzhen Grubbs Institute, Shenzhen 518055;
    d Sauvage Center for Molecular Sciences, Wuhan University, Wuhan 430072

Received date: 2019-03-22

  Revised date: 2019-04-23

  Online published: 2019-05-06

Supported by

Project supported by the National Natural Science Foundation of China (No. 21871212) and the Natural Science Foundation of Hubei Province (No. 2018CFB430).

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Abstract

Asymmetric hydroformylation is one of the most important reactions for preparation of chiral aldehydes from alkenes. Recently, significant progress has been made in this field and a series of new ligands have been developed. Asymmetric hydroformylation of several important alkenes has been achieved, offering efficient and concise methods for the synthesis of chiral aldehydes. In this review, the achievements of asymmetric hydroformylation of typical alkenes and the development of ligands for asymmetric hydroformylation are summarized.

Key words： alkene; asymmetric hydroformylation; aldehyde; chiral phosphine ligand; rhodium

Cite this article

Li Shuailong, Li Zhuangxing, You Cai, Lü Hui, Zhang Xumu . Recent Advances in Asymmetric Hydroformylation[J]. Chinese Journal of Organic Chemistry, 2019 , 39(6) : 1568 -1582 . DOI: 10.6023/cjoc201903044

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