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Chinese Journal of Organic Chemistry >

2019 , Vol. 39 >Issue 10: 2980 - 2984

DOI: https://doi.org/10.6023/cjoc201904001

NOTES

Synthesis and Application of Fluorescent Probe Containing Barbitone Unit

  • Yu Liu, ,
  • Yongxing Tang, ,
  • Yueyang Luo, ,
  • Yeting Zhu, ,
  • Jin Yang, ,
  • Xinyu Wei, ,
  • Xiong Liu, ,
  • Yunhui Zhao,
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  • a National Engineering Laboratory for Wheat & Corn Further Processing, Henan University of Technology, Zhengzhou 450001;
    b Key Laboratory of Synthetic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032
    c Hunan Provincial Key Laboratory of Controllable Preparation and Functional Application of Fine Polymers, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201

Received date: 2019-04-01

  Revised date: 2019-05-05

  Online published: 2019-05-21

Supported by

Project supported by the Open Project of the National Engineering Laboratory for Wheat & Corn Further Processing, Henan University of Technology(No. NL2018006)

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Abstract

Mercury ion pollution has serious harmful impact on the ecological environment and human health. It is of great significance to develop a probe with high selectivity and sensitivity that could be applied to the detection of mercury ion in water environment. In this paper, a novel excited-state intramolecular proton transfer (ESIPT) fluorescent probe containing barbitone unit was designed and synthesized from salicylaldehyde. Mechanism studies showed that mercury ions and probes formed a structure similar to “(thymine)T-Hg-T” which has high selectivity in determining mercury ions. The calibration curve indicated that there was a good linear correlation between the relative fluorescent intensities over the concentration range of 4~20 μmol·L –1 of Hg 2+ ion.

Key words： fluorescent probe; mercury ion; barbitone; excited-state intramolecular proton transfer (ESIPT)

Cite this article

Yu Liu, , Yongxing Tang, , Yueyang Luo, , Yeting Zhu, , Jin Yang, , Xinyu Wei, , Xiong Liu, , Yunhui Zhao, . Synthesis and Application of Fluorescent Probe Containing Barbitone Unit[J]. Chinese Journal of Organic Chemistry, 2019 , 39(10) : 2980 -2984 . DOI: 10.6023/cjoc201904001

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