Chinese Journal of Organic Chemistry >
A Novel Method for the Synthesis Triarylphosphines under Transition-Metal-Free Conditions
Received date: 2019-04-02
Revised date: 2019-04-26
Online published: 2019-05-21
Supported by
Project supported by the National Natural Science Foundation of China(Nos. 21572028);Project supported by the National Natural Science Foundation of China(21573032)
Triarylphosphines play an important role in pharmaceutical synthesis and transition-meal-catalyzed reactions. In this paper, a novel method for the synthesis of triarylphosphines via base-promoted C(sp 2)—P cross-coupling reactions of alkyldiphenylphosphines with aryl halides is described. The transition-metal-free reaction condition, readily available starting materials and experimental simplicity are the features of the novel method.
Qing Yin, , Xiaoqiang Yu, , Ming Bao, . A Novel Method for the Synthesis Triarylphosphines under Transition-Metal-Free Conditions[J]. Chinese Journal of Organic Chemistry, 2019 , 39(10) : 2930 -2935 . DOI: 10.6023/cjoc201904006
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