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Chinese Journal of Organic Chemistry >

2019 , Vol. 39 >Issue 10: 2771 - 2785

DOI: https://doi.org/10.6023/cjoc201904061

REVIEW

Research Progress in Design, Synthesis and Application of Benzo Nitrogen-Containing Heterocyclic Fluorescent Probes

  • Neng Wang ,
  • Mani Arulkumar ,
  • Xiaoyun Chen ,
  • Bowen Wang ,
  • Sihong Chen ,
  • Chen Yao ,
  • Zhaoyang Wang
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  • a Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, Guangzhou Key Laboratory of Analytical Chemistry for Biomedicine, School of Chemistry, South China Normal University, Guangzhou 510006
    b School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003

Received date: 2019-04-25

  Revised date: 2019-05-14

  Online published: 2019-06-03

Supported by

Project supported by the National Natural Science Foundation of China(21602085);The Natural Science Foundation of Guangdong Province(2014A030313429);The Guangzhou Science and Technology Project Scientific Special(201607010251);The Natural Science Foundation of Jiangsu Province(BK20160551);The Guangdong Provincial Science and Technology Project(2017A010103016);The Undergraduates Innovation Project of South China Normal University(20191434)

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Abstract

Benzo five-/six-membered nitrogen-containing heterocyclic compound with a rigid plane and a large conjugate structure can emit characteristic fluorescence in a variety of organic solvents and mixed solutions, and N, O, S heteroatoms in the structure can serve as binding sites for fluorescent probes. Therefore, in recent years, benzo nitrogen-containing heterocyclic compounds are increasingly becoming one of the research focuses in the field of fluorescent probes. From the perspective of starting materials, synthesis methods, molecular structure, interaction mechanism, benzo five- / six-membered nitrogen-containing heterocyclic fluorescent probes containing the structure of benzoxazole, benzothiazole, benzimidazole, indole, carbazole, quinoline, benzopyrazine and phenazine are introduced with emphasis. And their detection application for a variety of analytes, such small molecules, metal cations, anions and pH are reviewed. In the future, it is worthy of further attention to the research on the integration of multiple heterocyclic functional structures into a multifunctional fluorescent probe by simple and green synthesis.

Key words： benzo five-membered nitrogen heterocycle; benzo six-membered nitrogen heterocycle; fluorescent probe; design and synthesis; recognition mechanism; detection application; multifunctionalization

Cite this article

Neng Wang , Mani Arulkumar , Xiaoyun Chen , Bowen Wang , Sihong Chen , Chen Yao , Zhaoyang Wang . Research Progress in Design, Synthesis and Application of Benzo Nitrogen-Containing Heterocyclic Fluorescent Probes[J]. Chinese Journal of Organic Chemistry, 2019 , 39(10) : 2771 -2785 . DOI: 10.6023/cjoc201904061

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