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Chinese Journal of Organic Chemistry >

2019 , Vol. 39 >Issue 11: 3114 - 3131

DOI: https://doi.org/10.6023/cjoc201903029

Advances on Directing-Group Assisted meta-C-H Functionalization Catalyzed by Transition Metal

  • Mei Wu ,
  • Xinping Huang ,
  • Haibing Zhang ,
  • Pengfei Li
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  • a State Key Laboratory of Heavy Oil Processing, China University of Petroleum-Beijing At Karamay, Karamay, Xingjiang 834000
    b Petrochina Karamay Petrochemical CO. LTD, Karamay, Xingjiang 834000

Received date: 2019-03-15

  Online published: 2019-06-19

Supported by

the Science Foundation of China University of Petroleum-Beijing at Karamay(RCYJ2016B-03-003)

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Abstract

Transition-metal-catalyzed functionalization of unactivated C-H bonds is a highly attractive strategy for the synthesis of organic molecules, however, regioselective control is a central challenge in this field. The directing group assisted C-H functionalizations such as the use of directing templates and transient mediator, secondary interaction have attracted more attentions from researchers. The meta-C-H functionalizatioin assisted by directing groups are summarized in details. The existing problems and limitations of this field are also included. Finally, the development trend of this area is prospected.

Key words： directed by template; meta-activation; C-H functionalization; secondary interaction; transient mediator

Cite this article

Mei Wu , Xinping Huang , Haibing Zhang , Pengfei Li . Advances on Directing-Group Assisted meta-C-H Functionalization Catalyzed by Transition Metal[J]. Chinese Journal of Organic Chemistry, 2019 , 39(11) : 3114 -3131 . DOI: 10.6023/cjoc201903029

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