Chinese Journal of Organic Chemistry >
Palladium-Catalyzed Regioselective ortho-Acylation of Azoxybenzenes under Aqueous Conditions
Received date: 2019-05-09
Online published: 2019-07-09
Supported by
the Key Scientific Research Project for Colleges and Universities of Henan Province(20A150019);the Doctoral Research Startup Fund of Henan University of Animal Husbandry and Economy(53000168)
A facile and efficient protocol for palladium-catalyzed ortho-acylation of azoxybenzenes has been developed under aqueous conditions. In this process, the alcohols were oxidized into the corresponding aldehydes in situ, which coupled with azoxybenzenes with excellent regioselectivity, affording the acylated azoxybenzenes in moderate to good yields. A variety of functional groups were tolerated in this procedure.
Xiaopei Chen , Zhiwei Ma , Chuanchuan Wang , Juntao Liu , Jinsong Wu . Palladium-Catalyzed Regioselective ortho-Acylation of Azoxybenzenes under Aqueous Conditions[J]. Chinese Journal of Organic Chemistry, 2019 , 39(11) : 3176 -3182 . DOI: 10.6023/cjoc201905017
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