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Chinese Journal of Organic Chemistry >

2019 , Vol. 39 >Issue 12: 3363 - 3374

DOI: https://doi.org/10.6023/cjoc201906026

Progress in Co-Catalyzed C-H Amination

  • Sun Yiming ,
  • Ding Qifeng ,
  • Yu Yang ,
  • He Yide ,
  • Huang Fei
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  • a College of Pharmacy, Nanjing Tech University, Nanjing 211816;
    b College of Food and Pharmaceutical Engineering, Nanjing Normal University, Nanjing 210023;
    c School of Environmental and Engineering, Nanjing Tech University, Nanjing 211816

Received date: 2019-06-20

  Revised date: 2019-07-24

  Online published: 2019-08-07

Supported by

Project supported by the Postdoctoral Science Foundation of China (No. 2019M651809), the Jiangsu Synergetic Innovation Center for Advanced Bio-manufacture (Nos. XTE1850, XTC1810), the Postdoctoral Science Foundation of Anhui Province (No. 2018B252) and the Natural Science Foundation of Jiangsu Province (No. BK20160989).

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Abstract

Amino compounds have a wide range of applications in the fields of organic chemistry, medicinal chemistry and functional materials. The efficient construction of C-N bonds has important research significance. Conventional amination reactions to construct C-N bonds require pre-functionalization of the substrate and inevitably produce quantitative halogenate by-products. The C-H amination reaction is directly based on hydrocarbons. The reaction has the advantages of "step" and "atomic" economy, in line with the green chemistry concept. Transition metal cobalt has the advantage of low toxicity and low cost. As a catalyst for C-H amination reaction, it exhibits its unique catalytic properties and attracts the attention of chemists. The research progress of cobalt-catalyzed C-H amination in recent years is summarized. At the same time, the challenges and development prospects of the research field are summarized and forecasted.

Key words： cobalt catalysis; C-H amination; amino compound

Cite this article

Sun Yiming , Ding Qifeng , Yu Yang , He Yide , Huang Fei . Progress in Co-Catalyzed C-H Amination[J]. Chinese Journal of Organic Chemistry, 2019 , 39(12) : 3363 -3374 . DOI: 10.6023/cjoc201906026

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