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Chinese Journal of Organic Chemistry >

2019 , Vol. 39 >Issue 12: 3328 - 3337

DOI: https://doi.org/10.6023/cjoc201907005

Recent Advances of Transition Metal-Catalyzed Aerobic Oxygenation with Molecular Oxygen

  • Wu Jinwen ,
  • Zhu Jiawen ,
  • Li Hui ,
  • Wu Chunlei ,
  • Shen Runpu ,
  • Yu Lemao
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  • College of Chemistry and Chemical Engineering, Shaoxing University, Shaoxing, Zhejiang 312000

Received date: 2019-07-03

  Revised date: 2019-08-11

  Online published: 2019-08-30

Supported by

Project supported by the Public Projects of Zhejiang Province of China (No. LGG19B02002) and the Doctoral Research Initiation Fund of Shaoxing University (No. 20185018).

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Abstract

Oxygen-bearing structures are attractive synthetic targets due to their wide presence in a great number of natural products and biologically active molecules, and their role as useful synthons in organic synthesis. Thus, the preparation of O-bearing compounds has been an important topic. Transition metal-catalyzed aerobic oxygenation strategy has emerged as a novel and efficient methodology for constructing C-C bonds and C-heteroatom bonds. This strategy has become one of the most important and useful synthetic method in organic synthesis of O-bearing compounds. Based on the previous work of our group and others, herein, the new applications of transition metal-catalyzed oxygenation of C-H bond activation and C-C bond cleavage with oxygen as oxygen source are discussed. The recent progress in trans-metal catalytic oxygen insertion of ketones, aldehydes, alkene, alkynes, arene and aromatic heterocyclic compounds has been reviewed. Transition metal-catalysts can initiate oxygen insertion reaction of free radical pathway and realize selective insertion of oxygen radicals under oxygen oxidation. These reactions are characterized by mild conditions, environmental protection and highly atom economy.

Key words： transition metal catalysis; oxygen oxidation; C-H activation; C-C cleavage; oxygenated reaction; radical pathway

Cite this article

Wu Jinwen , Zhu Jiawen , Li Hui , Wu Chunlei , Shen Runpu , Yu Lemao . Recent Advances of Transition Metal-Catalyzed Aerobic Oxygenation with Molecular Oxygen[J]. Chinese Journal of Organic Chemistry, 2019 , 39(12) : 3328 -3337 . DOI: 10.6023/cjoc201907005

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