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Chinese Journal of Organic Chemistry >

2019 , Vol. 39 >Issue 12: 3467 - 3474

DOI: https://doi.org/10.6023/cjoc201907010

Decarboxylative Oxyphosphorylation of Alkynyl Carboxylic Acids with H-Phosphonates Catalyzed by Cu-Cu2O/GO-NH2

  • Zhong Wenwu ,
  • Tang Qian ,
  • Yang Zongfa ,
  • Zeng Xue ,
  • Gan Linling ,
  • Lan Zuoping ,
  • Yang Yuanjuan
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  • a Chongqing Medical and Pharmaceutical College, Chongqing 401331;
    b Chongqing Engineering Technology Research Center of Pharmaceutical Sciences, Chongqing 401331;
    c National Second-level Scientific Research Laboratory of the Quality Testing of Traditional Chinese Medicine, Chongqing 401331

Received date: 2019-07-04

  Revised date: 2019-08-13

  Online published: 2019-08-30

Supported by

Project supported by the Scientific Research Project of Chongqing Medical and Pharmaceutical College (Nos. ygz2018303, ygz2018102), the Medical Scientific Research Project of Chongqing Municipal Health and Family Planning Commission (Nos. 2012-1-093, 20142116), the Chinese Medicine Science and Technology Project of Chongqing Municipal Health and Family Planning Commission (No. ZY201402158), and the Scientific and Technological Research Project of Chongqing Municipal Education Commission (No. KJ1726394).

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Abstract

A graphene based hybrid with copper nanoparticles (Cu-Cu2O/GO-NH2) as a heterogeneous catalyst for the preparation of β-ketophosphonates was investigated. Compared with traditional homogeneous catalysis, Cu-Cu2O/GO-NH2 catalyst can be recovered from the reaction system. The present methodology provides a facile and efficient approach to access a wide range of β-ketophosphonates in good yields. This reaction can be conducted under base-free conditions without any external co-catalysts, which provides an alternative strategy for the synthesis of β-ketophosphonates.

Key words： Cu nanoparticles; graphene; oxyphosphorylation; heterogeneous catalysis; β-ketophosphonates

Cite this article

Zhong Wenwu , Tang Qian , Yang Zongfa , Zeng Xue , Gan Linling , Lan Zuoping , Yang Yuanjuan . Decarboxylative Oxyphosphorylation of Alkynyl Carboxylic Acids with H-Phosphonates Catalyzed by Cu-Cu2O/GO-NH2[J]. Chinese Journal of Organic Chemistry, 2019 , 39(12) : 3467 -3474 . DOI: 10.6023/cjoc201907010

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