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Chinese Journal of Organic Chemistry >

2020 , Vol. 40 >Issue 3: 625 - 644

DOI: https://doi.org/10.6023/cjoc201909015

Recent Advances in Ligand-Promoted Transition-Metal-Catalyzed Remote meta-C—H Functionalization of Arenes

  • Tian Wanfa ,
  • Li Na ,
  • Peng Zihe ,
  • Feng Lihua ,
  • Mai Xi ,
  • He Yongqin
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  • a School of Pharmaceutical Science, Nanchang University, Nanchang 330000;
    b Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330000;
    c Fuzhou Medical College, Nanchang University, Fuzhou, Jiangxi 344000

Received date: 2019-09-09

  Revised date: 2019-11-27

  Online published: 2019-12-19

Supported by

Project supported by the National Natural Science Foundation of China (No. 81860610) and the Young Teachers Training Foundation of Nanchang University (No. 4209-16100009-PY201810).

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Abstract

Ligands can regulate both the steric and electronic effects of the catalytic center in transition-metal-catalyzed C-H activation reactions, leading to the site-selective C-H functionalization of arenes. In recent years, ligand-promoted remote C-H functionalization of arenes has developed rapidly. The recent progress on ligand-promoted transition-metal-catalyzed remote meta-selective C-H bond functionalization of arenes is summarized, and the limitations of the research field and prospects for future development are presented.

Key words： transition metal catalysis; remote meta-C—H bond; functionalization; ligand promotion

Cite this article

Tian Wanfa , Li Na , Peng Zihe , Feng Lihua , Mai Xi , He Yongqin . Recent Advances in Ligand-Promoted Transition-Metal-Catalyzed Remote meta-C—H Functionalization of Arenes[J]. Chinese Journal of Organic Chemistry, 2020 , 40(3) : 625 -644 . DOI: 10.6023/cjoc201909015

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