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Chinese Journal of Organic Chemistry >

2020 , Vol. 40 >Issue 4: 873 - 885

DOI: https://doi.org/10.6023/cjoc201911009

Recent Advance in the Transition-Metal-Catalyzed Carbene Insertion Reactionsof Si—H Bond

  • Zhang Huimiao ,
  • Li Lingzhi ,
  • Shen Fangqi ,
  • Cai Tao ,
  • Shen Runpu
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  • a College of Chemistry and Chemical Engineering, Shaoxing University, Shaoxing, Zhejiang 312000;
    b College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070

Received date: 2019-11-06

  Revised date: 2019-12-04

  Online published: 2019-12-19

Supported by

Project supported by the Youth Foud of Shaoxing University (No. 20185019).

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Abstract

Organosilicon compounds have been widely used in organic synthesis, biomedicine, material science and other fields. The development of simple and efficient C——Si bond construction methodology has attracted extensive attention from scientists. Transition-metal-catalyzed carbene insertion reaction of Si——H bond is one of the important methods to form C——Si bond. It not only has the advantages of simple operation, mild reaction conditions and high atom economy, but also can be used to synthesize various chiral organosilanes with high enantioselectivity through the regulation of chiral ligands. In recent years, achieved rapid development has been in this field, and various new carbene precursors and metal catalytic systems have been emerged. According to the group of transition metal elements, recent advance in the iron, copper, zinc, ruthenium, rhodium, palladium, silver, iridium and gold catalyzed carbene insertion reactions of Si——H bond since 2012 is reviewed in five parts.

Key words： transition metal catalysis; metal carbene; Si—H bond insertion; C—Si bond formation; organosilane

Cite this article

Zhang Huimiao , Li Lingzhi , Shen Fangqi , Cai Tao , Shen Runpu . Recent Advance in the Transition-Metal-Catalyzed Carbene Insertion Reactionsof Si—H Bond[J]. Chinese Journal of Organic Chemistry, 2020 , 40(4) : 873 -885 . DOI: 10.6023/cjoc201911009

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