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Chinese Journal of Organic Chemistry >

2020 , Vol. 40 >Issue 7: 1805 - 1813

DOI: https://doi.org/10.6023/cjoc202003048

ACCOUNTS

Recent Advances in Trifluoromethoxylation Reactions

  • Wang Feng ,
  • Tang Pingping
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  • State Key Laboratory of Elemento-organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071

Received date: 2020-03-20

  Revised date: 2020-04-24

  Online published: 2020-04-30

Supported by

Project supported by the National Key Research and Development Program of China (No. 2016YFA0602900), the National Natural Science Foundation of China (Nos. 21672110, 21925105) and the Natural Science Foundation of Tianjin City (No. 18JCJQJC47000).

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Abstract

In recent years, the field of organic fluorine chemistry has developed rapidly. Fluorination and fluorine-containing functionalization reactions have attracted extensive attention of organic chemists due to their special physical and chemical properties. The introduction of fluorine-containing group into drug molecules can improve the biological activity of drug molecules. Trifluoromethoxy group has strong electron absorption and high lipophilicity, compounds containing trifluoromethoxy play an important role in the fields of medicine, pesticides and materials. In recent years, some innovative strategies have been used to synthesize compounds containing trifluoromethoxy group. This account mainly focuses on the research of trifluoromethoxy reaction in our group, and some challenges faced by trifluoromethoxy reaction.

Key words： trifluoromethoxylation; trifluoromethyl aryl sulfonate (TFMS); (E)-O-trifluoromethyl-benzaldoximes (TFBO)

Cite this article

Wang Feng , Tang Pingping . Recent Advances in Trifluoromethoxylation Reactions[J]. Chinese Journal of Organic Chemistry, 2020 , 40(7) : 1805 -1813 . DOI: 10.6023/cjoc202003048

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