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Chinese Journal of Organic Chemistry >

2020 , Vol. 40 >Issue 10: 3279 - 3288

DOI: https://doi.org/10.6023/cjoc202004022

Organic Reactions in Covalent Functionalization of Graphene

  • Hao Bingjie ,
  • Song Tao ,
  • Huang Xiaoyu ,
  • Ye Mao ,
  • Qian Wenhao
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  • a Department of Stomatology, Shanghai Xuhui District Dental Center, Shanghai 200032;
    b Shanghaitech University, School of Physical Science and Technology, Shanghai 201210;
    c Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Shanghai 200032

Received date: 2020-04-14

  Revised date: 2020-05-04

  Online published: 2020-05-11

Supported by

Project supported by the National Natural Science Foundation of China (No. 51773222), the Shanghai Scientific and Technological Innovation Project (No. 20ZR1452200), the Scientific Research Project of Science and Technology Commission of Xuhui Municipality (No. SHXH201613), the Scientific Research Project of Xuhui Provincial Commission of Health and Family Planning (No. SHXH201706), the Program for Outstanding Medical Academic Leader (No. 2019LJ27) and the Shanghai Medical Key Specialty (No. ZK2019B12).

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Abstract

Graphene and graphene oxide possess unique structure and excellent properties, and have become popular potential materials in biology, information, energy and other fields in recent years. The high-quality nanocomposites were obtained by hybridizing graphene-based materials with functional molecules, polymers and nanoparticles. Besides the modification via weak interaction, covalent modification of graphene and graphene oxide via organic reaction can stably and effectively optimize the structure, enhance their performances and extend their applications. In this review, the diverse approaches of chemically covalent modification of graphene and graphene oxide are reviewed via esterification, acylation, Williamson reaction, Eschenmoser-Claisen[3,3] σ rearrangement and click chemistry, and the future development trend is prospected.

Key words： graphene; graphene oxide; covalent functionalization; organic reactions

Cite this article

Hao Bingjie , Song Tao , Huang Xiaoyu , Ye Mao , Qian Wenhao . Organic Reactions in Covalent Functionalization of Graphene[J]. Chinese Journal of Organic Chemistry, 2020 , 40(10) : 3279 -3288 . DOI: 10.6023/cjoc202004022

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