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Chinese Journal of Organic Chemistry >

2020 , Vol. 40 >Issue 7: 1926 - 1933

DOI: https://doi.org/10.6023/cjoc202003004

Selectfluor-Promoted Twofold Sulfination of Alcohols for the Synthesis of Sulfinic Ester from Diaryldisulfides

  • Liu Aiyao ,
  • Liu Jiang ,
  • Mei Haibo ,
  • Röschenthaler Gerd-Volker ,
  • Han Jianlin
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  • a Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China;
    b Shandong Key Laboratory of Biochemical Analysis, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China;
    c Department of Life Sciences and Chemistry, Jacobs University Bremen gGmbH, Bremen 28759, Germany

Received date: 2020-03-03

  Revised date: 2020-05-06

  Online published: 2020-05-15

Supported by

Project supported by the National Natural Science Foundation of China (No. 21761132021), the German Research Foundation (No. 362/74-1) and the Open Project of Chemistry Department of Qingdao University of Science and Technology (No. QUSTHX202005).

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Abstract

An oxidative twofold sulfination of alcohol with Selectfluor as an efficient oxidant was developed. This reaction proceeded smoothly achieving the unprecedented sulfination transformation of varieties of diaryldisulfides and alcohols under simple conditions, affording the corresponding sulfinic esters in excellent yields. The current reaction provides a new and convenient strategy for the preparation of sulfinic esters.

Key words： Selectfluor; disulfide; sufination; sulfinic ester; C-O bond cleavage

Cite this article

Liu Aiyao , Liu Jiang , Mei Haibo , Röschenthaler Gerd-Volker , Han Jianlin . Selectfluor-Promoted Twofold Sulfination of Alcohols for the Synthesis of Sulfinic Ester from Diaryldisulfides[J]. Chinese Journal of Organic Chemistry, 2020 , 40(7) : 1926 -1933 . DOI: 10.6023/cjoc202003004

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