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Chinese Journal of Organic Chemistry >

2020 , Vol. 40 >Issue 8: 2185 - 2194

DOI: https://doi.org/10.6023/cjoc202005017

ACCOUNT

Lewis-Base Boryl Radicals Enabled Borylation, Radical Catalysis and Reduction Reactions

  • Jin Jikang ,
  • Xia Huimin ,
  • Zhang Fenglian ,
  • Wang Yifeng
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  • Department of Chemistry, University of Science and Technology of China, Hefei 230026

Received date: 2020-05-07

  Revised date: 2020-05-19

  Online published: 2020-05-29

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 21672195, 21702201, 21971226) and the Fundamental Research Funds for the Central Universities (No. WK2060190082).

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Abstract

Free radical reactions represent an efficient and significant tool to construct organic molecules by taking advantages of the high-efficiency, remarkable selectivity and good functional groups tolerance. Lewis-base boryl radicals are a class of species that possess unique structures and chemical reactivity, and a variety of synthetic applications have been developed. This account summarizes the research advances in this research field mainly contributed by our group. The results include Lewis-based boryl radicals enabled borylation reactions, Lewis-based boryl radicals-catalyzed new reactions, and Lewis-based boryl radicals promoted reduction reactions. These reactions feature mild reaction conditions, good functional groups compatibility, high yields, and excellent chemo-, regio-, and stereo-selectivities.

Key words： Lewis-base boryl radicals; radical borylation reactions; radical catalysis; radical reduction reactions; free radical chemistry

Cite this article

Jin Jikang , Xia Huimin , Zhang Fenglian , Wang Yifeng . Lewis-Base Boryl Radicals Enabled Borylation, Radical Catalysis and Reduction Reactions[J]. Chinese Journal of Organic Chemistry, 2020 , 40(8) : 2185 -2194 . DOI: 10.6023/cjoc202005017

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