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Chinese Journal of Organic Chemistry >

2020 , Vol. 40 >Issue 12: 4290 - 4297

DOI: https://doi.org/10.6023/cjoc202005049

Nopinone-Based Difluoroboron β-Diketonate Complex: Aggregation-Induced Emission and Solvatochromism

  • Jiang Qian ,
  • Wang Zhonglong ,
  • Li Mingxin ,
  • Yang Yiqin ,
  • Xu Xu ,
  • Xu Haijun ,
  • Wang Shifa
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  • Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, College of Light Industry and Food, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037

Received date: 2020-05-19

  Revised date: 2020-06-23

  Online published: 2020-07-23

Supported by

Project supported by the National Natural Science Foundation of China (No. 31470592).

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Abstract

Three difluoroboron (BF2) β-diketonates 2a~2c including different aromatic ring systems were synthesized from nopinone which was the derivative of renewable natural β-pinene. In the solid state, compounds 2a~2c exhibit different fluorescent colors. Compounds 2b and 2c showed the positive solvatochromism phenomenon, and they have different fluorescence colors in different polar solvents. In addition, compounds 2b and 2c have significant aggregation-induced emission (AIE) effect. Compounds 2b and 2c were made into electroluminescent devices I and II, and device I and II emit green light and yellow light, respectively. The results indicate that compounds 2b and 2c have good application prospects as organic solid luminescent materials.

Key words： nopinone; β-diketonate; aggregation-induced emission (AIE) effect; solvatochromism

Cite this article

Jiang Qian , Wang Zhonglong , Li Mingxin , Yang Yiqin , Xu Xu , Xu Haijun , Wang Shifa . Nopinone-Based Difluoroboron β-Diketonate Complex: Aggregation-Induced Emission and Solvatochromism[J]. Chinese Journal of Organic Chemistry, 2020 , 40(12) : 4290 -4297 . DOI: 10.6023/cjoc202005049

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