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Chinese Journal of Organic Chemistry >

2020 , Vol. 40 >Issue 11: 3853 - 3857

DOI: https://doi.org/10.6023/cjoc202006055

Tris(trimethylsilyl)silane/O2-Promoted and Photo-accelerated Conversion of Alkyl Iodides to Alcohols

  • Li Jianyu ,
  • Zeng Jinlong ,
  • Chen Jianfeng ,
  • Zhao Baoguo
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  • Key Laboratory of Resource Chemistry of Ministry of Education and Shanghai Key Laboratory of Rare Earth Functional Materials, College of Chemistry and Materials Science, Shanghai Normal University, Shanghai 200234

Received date: 2020-06-26

  Revised date: 2020-08-05

  Online published: 2020-08-19

Supported by

Project supported by the National Natural Science Foundation of China (No. 21672148), the Shanghai Municipal Education Commission (No. 2019-01-07-00-02-E00029) and the Shanghai Engineering Research Center of Green Energy Chemical Engineering.

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Abstract

A mild method for the conversion of alkyl iodides to alcohols was developed. The transformation was promoted by tris(trimethylsilyl)silane/O2 and accelerated by photoredox catalysis under visible light irradiation conditions. Various alkyl iodides, including primary, secondary and tertiary iodides, can be smoothly converted to the corresponding alcohols in 38%~99% yields.

Key words： tris(trimethylsilyl)silane; photoredox catalysis; carbon radical; alkyl iodide; alcohol

Cite this article

Li Jianyu , Zeng Jinlong , Chen Jianfeng , Zhao Baoguo . Tris(trimethylsilyl)silane/O2-Promoted and Photo-accelerated Conversion of Alkyl Iodides to Alcohols[J]. Chinese Journal of Organic Chemistry, 2020 , 40(11) : 3853 -3857 . DOI: 10.6023/cjoc202006055

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