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Chinese Journal of Organic Chemistry >

2021 , Vol. 41 >Issue 1: 412 - 417

DOI: https://doi.org/10.6023/cjoc202007028

NOTES

A Green Method for the Synthesis of Sulfones from Thioethers

  • Xiang Fang ,
  • Wang Wang ,
  • Xueyan Yang ,
  • Fanhong Wu
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  • a School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237
    b Shanghai Engineering Research Center of Green Fluoropharmaceutical Technology, Shanghai Institute of Technology, Shanghai 201418

Received date: 2020-07-09

  Revised date: 2020-07-30

  Online published: 2020-08-27

Supported by

the National Natural Science Foundation of China(21672151)

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Abstract

With water as oxygen source, a method for the synthesis of sulfones from thioethers under the action of Selecetfluor TM was designed. The yield can reach 99%. The 18O-labeled methylphenylsulfone was prepared with H2 18O. The conditions of this green method are mild and can reach the grams scale.

Key words： thioethers; SelecetfluorTM; water; sulfone compound

Cite this article

Xiang Fang , Wang Wang , Xueyan Yang , Fanhong Wu . A Green Method for the Synthesis of Sulfones from Thioethers[J]. Chinese Journal of Organic Chemistry, 2021 , 41(1) : 412 -417 . DOI: 10.6023/cjoc202007028

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